Department of Physical Chemistry

Nanostructured Model Catalysts

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Dr. Eva-Maria Köck

Photo of Eva-Maria Köck

Contact

Telephone: +43 512 507 57043

Email: eva-maria.koeck@uibk.ac.at

Room: L.01.040



Theses

Type
Year
Title
Supervisor(s)
PhD
2016
FTIR spectroscopy investigations of Metal-Support Interactions on SOFC-relevant Metal-Oxide Systems
Klötzer, Bernhard; Penner, Simon
Diploma
2012
Charakterisierung der Reaktivität von ZrO2, Y2O3 und YSZ gegenüber den Komponenten der Wasser-Gas-Shift Reaktion durch FTIR-Spektroskopie
Klötzer, Bernhard; Penner, Simon

Publications (19)

19.
; ; ; ; ; ; ; ; ; ; ; Water adsorption at zirconia: From the ZrO2(111)/Pt3Zr(0001) model system to powder samples . J. Mater. Chem. A 6, 17587-17601
18.
; ; ; ; ; ; ; Li3Co1.06(1)TeO6: synthesis, single-crystal structure and physical properties of a new tellurate compound with CoII/CoIII mixed valence and orthogonally oriented Li-ion channels. Dalton Trans. 46 (37), 12663-12674
17.
; ; ; ; ; ; ; ; ; ; ; Surface chemistry of pure tetragonal ZrO2 and gas-phase dependence of the tetragonal-to-monoclinic ZrO2 transformation. Dalton Trans. 46 (14), 4554-4570
16.
; ; ; ; ; ; ; Surface chemistry and stability of metastable corundum-type In2O3. Phys. Chem. Chem. Phys. 19 (29), 19407-19419
15.
; ; ; ; ; ; ; ; Novel Molecular Spectroscopic Multimethod Approach for Monitoring Water Absorption/Desorption Kinetics of CAD/CAM Poly(Methyl Methacrylate) Prosthodontics. Appl. Spectrosc. 71 (7), 1600-1612
14.
; ; ; ; Evidence for dissolved hydrogen in the mixed ionic-electronic conducting perovskites La0.6Sr0.4FeO3-d and SrTi0.7Fe0.3O3-d. Phys. Chem. Chem. Phys. 18, 26873 - 26884
13.
; ; ; ; Structural and Chemical Degradation Mechanisms of Pure YSZ and Its Components ZrO2 and Y2O3 in Carbon-Rich Fuel Gases. Phys. Chem. Chem. Phys. 18, 14333-14349
12.
; ; ; ; Structural and Electrochemical Properties of Physisorbed and Chemisorbed Water Layers on the Ceramic Oxides Y2O3, YSZ, and ZrO2. ACS Appl. Mater. Interfaces 8 (25), 16428-16443
11.
; ; ; ; ; ; ; ; Metastable Corundum-Type In2O3: Phase Stability, Reduction Properties and Catalytic Characterization. J. Phys. Chem. C 120, 15272–15281
10.
; ; ; Structure–Property Relationships in the Y2O3–ZrO2Phase Diagram: Influence of the Y-Content on Reactivity in C1 Gases, Surface Conduction, and Surface Chemistry. J. Phys. Chem. C 120 (39), 22443-22454
9.
; ; ; ; Surface Reactivity of YSZ, Y2O3 and ZrO2 Towards CO, CO2 and CH4: A Comparative Discussion. J. Phys. Chem. C 120, 3882-3898
8.
; ; ; ; ; ; ; ; High-Temperature Carbon Deposition on Oxide Surfaces by CO Disproportionation. J. Phys. Chem. C 120 (3), 1795-1807
7.
; ; ; ; ; ; Distinct Carbon Growth Mechanisms on the Components of Ni/YSZ Materials. Mater. Chem. Phys. 173, 508-515
6.
; ; ; ; A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy. Rev. Sci. Instrum. 85 (8), 084102
5.
; ; ; ; ; ; ; Hydrogen Surface Reactions and Adsorption Studied on Y2O3, YSZ, and ZrO2. J. Phys. Chem. C 118 (16), 8435-8444
4.
; ; ; ; ; ; ; ; ; ; Methane Decomposition and Carbon Growth on Y2O3, Yttria-Stabilized Zirconia, and ZrO2. Chem. Mater. 26 (4), 1690-1701
3.
; ; ; ; ; ; ; ; Enhanced Kinetic Stability of Pure and Y-Doped Tetragonal ZrO2. Inorg. Chem. 53 (24), 13247-13257
2.
; ; ; ; In Situ FT-IR Spectroscopic Study of CO2 and CO Adsorption on Y2O3, ZrO2, and Yttria-Stabilized ZrO2. J. Phys. Chem. C 117 (34), 17666-17673
1.
; ; ; ; ; ; ; ; ; Methanol steam reforming: CO2-selective Pd2Ga phases supported on α- and γ-Ga2O3. Appl. Catal. A 453, 34-44

* These authors contributed equally to the respective publication.

# This author was the corresponding author.

Talks (16)

Talks (2)

2.
Hydrogen Adsorption and Reactivity studied on Y2O3, YSZ and ZrO2
Köck, E.-M.*; Kogler, M.*; Schmidmair, D.; Perfler, L.; Willinger, M.; Klötzer, B.; Penner, S.
3rd Annual SFB FOXSI PhD Workshop, ÖTK Schutzhaus Hochkar, Göstling/Ybbs, Austria
07.04.201410.07.2014
1.
In-Situ FT-IR Spectroscopic Study of CO2 and CO Adsorption on Y2O3, ZrO2 and Yttria-Stabilized ZrO2
Köck, E.-M.; Kogler, M.; Klötzer, B.; Penner, S.; Perfler, L.
15th Austrian Chemistry Days (Joint Meeting of the Hungarian & Austrian Chemical Societies), Graz University of Technology, Austria
23.09.201326.09.2013

Contributed Talks (5)

5.
Catalytic Synergisms at (Bi)Metallic and Oxidic Phase Boundaries and Interfaces
Klötzer, B.; Penner, S.; Mayr, L.; Thalinger, R.; Köck, E.-M.; Kogler, M.; Götsch, T.
SFB F45 Interim Review Hearing, Haus der Forschung (FWF Building), Vienna, Austria
14.10.2014
4.
Catalytic Synergisms at (Bi)Metallic and Oxidic Phase Boundaries and Interfaces
Klötzer, B.; Penner, S.; Mayr, L.; Thalinger, R.; Köck, E.-M.; Kogler, M.
3rd Annual SFB FOXSI Symposium 2014, Conference Center Burg Schlaining, Stadtschlaining, Austria
21.09.201423.09.2014
3.
Model investigations of SOFC-relevant reforming processes
Klötzer, B.; Penner, S.; Mayr, L.; Thalinger, R.; Köck, E.-M.; Kogler, M.
2nd Annual SFB FOXSI Symposium 2013, Conference Center Burg Schlaining, Stadtschlaining, Austria
18.09.201320.09.2013
2.
TEM Studies of Carbon Deposition on YSZ and Y2O3
Kogler, M.; Köck, E.-M.; Penner, S.; Willinger, M.; Schuster, M.; Klötzer, B.
Annual Symposium of the SFB F45 „Functional Oxide Surfaces and Interfaces“ (FOXSI), Conference Center Burg Schlaining, Stadtschlaining, Austria
18.09.201320.09.2013
1.
Catalytic synergisms at bimetallic and oxidic phase boundaries and interfaces
Klötzer, B.; Penner, S.; Mayr, L.; Thalinger, R.; Köck, E.-M.; Kogler, M.
Kick-Off Meeting of SFB "FOXSI", TU Vienna, Austria
22.09.201123.09.2011

Poster Presentations (9)

9.
Structure-activity relationships in methanol steam reforming on Cu/t-ZrO2-catalysts
Ploner, K.; Köck, E.-M.; Wallisch, W.; Klötzer, B.; Penner, S.
International FOXSI Conference, Vienna, Austria
23.05.201625.05.2016
8.
A high-temperature, ambient-pressure ultra-dry operando reactor cell for FT-IR Spectroscopy
Köck, E.-M.; Kogler, M.; Klötzer, B.; Pramsoler, R.
5th Conference on Operando Spectroscopy, Deauville, France
17.05.201521.05.2015
7.
In Situ FT-IR Spectroscopic Study of CO2 and CO Adsorption on Y2O3, ZrO2, and Yttria-Stabilized ZrO2
Köck, E.-M.; Penner, S.; Klötzer, B.
GÖCH-Symposium „Physikalische Chemie in Österreich“, Montanuniversität Leoben, Austria
28.04.201429.04.2014
6.
Methane decomposition and carbon deposition on YSZ and Y2O3
Kogler, M.; Köck, E.-M.; Penner, S.; Willinger, M.; Schuster, M.; Klötzer, B.
GÖCH-Symposium „Physikalische Chemie in Österreich“, Montanuniversität Leoben, Austria
28.04.201429.04.2014
5.
Characterization of the reactivity of Y2O3, YSZ and ZrO2 towards the components of the WGSR using in-situ FT-IR-Spectroscopy
Köck, E.-M.; Kogler, M.; Penner, S.; Klötzer, B.
Annual Symposium of the SFB F45 „Functional Oxide Surfaces and Interfaces“ (FOXSI), Conference Center Burg Schlaining, Stadtschlaining, Austria
18.09.201320.09.2013
4.
Characterization of the reactivity of Y2O3, YSZ and ZrO2 towards the components of the WGSR using in-situ FT-IR-Spectroscopy
Köck, E.-M.; Kogler, M.; Penner, S.; Klötzer, B.
2nd Annual SFB FOXSI PhD Workshop, ÖTK Schutzhaus Hochkar, 3345 Göstling/Ybbs, Austria
18.03.201321.03.2013
3.
In-Situ Electrochemical Impedance Spectroscopy on Y2O3 and YSZ
Kogler, M.; Köck, E.-M.; Penner, S.; Klötzer, B.
2nd Annual SFB FOXSI PhD Workshop, ÖTK Schutzhaus Hochkar, 3345 Göstling/Ybbs, Austria
18.03.201321.03.2013
2.
In-Situ FTIR and EIS-Investigations of WGSR on Yttria
Köck, E.-M.; Kogler, M.; Penner, S.; Klötzer, B.
1st Annual SFB FOXSI Symposium, Conference Center Burg Schlaining, Stadtschlaining, Austria
26.09.201228.09.2012
1.
In-Situ FTIR and EIS-Investigations of WGSR on Yttria
Kogler, M.; Köck, E.-M.; Penner, S.; Klötzer, B.
ICC Satellite Workshop "ln situ Spectroscopy and Model Catalysis", Kloster Andechs, Germany
07.07.2012

Awards

3.
Eduard-Wallnöfer-Preis 2014
Köck, E.-M.; Kogler, M.
Tiroler Industriellenvereinigung
2.
CAST Technology Award 2014 (1st Place)
Köck, E.-M.; Penner, S.; Klötzer, B.; Pramsoler, R.
Center for Academic Spin-Offs Tirol
1.
Top Master 2013
Köck, E.-M.
Der Standard

Teaching

Course List

Term
Type
Course Nr.
Title
Lecturers
ECTS Points
Institution
2016S
Lab Course (6 h)
Practical course Physical Chemistry I
Dürrbeck, Stefan; Thomas Götsch; Huber, Veronika; Bernhard Klötzer; Eva-Maria Köck; Norbert Köpfle; Kunze-Liebhäuser, Julia; Lörting, Thomas; Memmel, Norbert; Menzel, Alexander
5
University of Innsbruck
2015W
Lab Course (6 h)
Lab-course in Physical Chemistry II
Bikaljevic, Djuro; Thomas Götsch; Huber, Veronika; Bernhard Klötzer; Eva-Maria Köck; Michaela Kogler; Kunze-Liebhäuser, Julia; Lörting, Thomas; Lukas Mayr; Memmel, Norbert; Menzel, Alexander; Ramona Thalinger
5
University of Innsbruck
2013S
Lab Course (6 h)
Practical course physical chemistry I
Thomas Bielz; Handle, Philip; Bernhard Klötzer; Eva-Maria Köck; Michaela Kogler; Lukas Mayr; Memmel, Norbert; Menzel, Alexander; Mitterdorfer, Christian; Seidl, Markus; Ramona Thalinger
6
University of Innsbruck